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Fluorine

physical science Maturity 11-13

Fluorine is a pale yellow gas.

Fluorine molecule ball.svg
Fluorine molecule ball.svg
It is very strong. It likes to join with other things. It helps keep your teeth healthy. You can find it in toothpaste.
US Navy 090526-F-1333S-023 A service member embarked aboard the Military Sealift Command hospital ship USNS Comfort (T-AH 20) gives a Fluoride treatment to a patient during a Continuing Promise 2009 medical civil service projec.jpg
US Navy 090526-F-1333S-023 A service member embarked aboard the Military Sealift Command hospital ship USNS Comfort (T-AH 20) gives a Fluoride treatment to a patient during a Continuing Promise 2009 medical civil service projec.jpg
Do you brush your teeth?

71 words

Fluorine is a pale yellow gas.

Fluorine molecule ball.svg
Fluorine molecule ball.svg
It is very strong. It likes to join with other things. This makes it react with almost everything.
HF burned hands.jpg
HF burned hands.jpg

It can be dangerous. It can hurt people if they touch it. Early scientists even died trying to study it.

We find it in rocks called fluorite. People use these rocks to make steel. This helps the metal melt more easily.

Book9-25.gif
Book9-25.gif

Fluorine helps keep your teeth healthy. It is often put in toothpaste. It can also be found in water.

Some things use it to stay cool. It is used in tools that keep things cold. It is a very useful part of our world.

116 words

Fluorine is a pale yellow gas.

Fluorine molecule ball.svg
Fluorine molecule ball.svg
It is a very active element. This means it likes to join with other things. It reacts with almost every other element. It only leaves a few noble gases alone.

Fluorine can be dangerous. In its pure form, it is highly toxic. Early scientists faced many risks. Some even died while trying to separate it from other things. In 1886, Henri Moissan finally isolated it. He used a way called electrolysis. This uses electricity to cause changes in a liquid.

Recherches sur l’isolement du fluor, Fig. 5.PNG
Recherches sur l’isolement du fluor, Fig. 5.PNG

We find fluorine in rocks like fluorite.

Book9-25.gif
Book9-25.gif
People add fluorite to metal ores. This helps the metal melt during smelting. Fluorine is also used to make aluminium. It helps in a part called cryolite.

Fluorine helps your teeth. Small bits called fluoride ions help stop cavities. You can find them in toothpaste and water. Some medicines also use fluorine. It is even used in Teflon. This makes things like non-stick pans work well.

170 words

Fluorine is a very active chemical element.

Fluorine molecule ball.svg
Fluorine molecule ball.svg
It usually exists as a pale yellow gas. This gas is made of two atoms joined together. Fluorine is the lightest of the halogen group. It is famous for being extremely reactive. This means it wants to join with almost every other element. It only leaves a few light noble gases alone. Because it reacts so easily, pure fluorine is highly toxic.
HF burned hands.jpg
HF burned hands.jpg
It is a powerful part of our world.

How does fluorine work in reactions? It has a very high electronegativity. This means it has a strong pull on electrons. An atom of fluorine has nine electrons in total. Seven of these are in its outer shell. It only needs one more electron to be full. This drive to grab an electron makes it very reactive. When it meets other things, it forms very strong bonds. For example, the bond between carbon and fluorine is very stable. This strength is why fluorine is used in many tools.

People have studied fluorine for a long time. In 1529, Georgius Agricola described a mineral called fluorite. He used the Latin word for "flow" to name it. People added this mineral to metal ores to help them melt. In 1810, André-Marie Ampère suggested the name fluorine. It was very hard to separate the element from other things. Many early scientists were injured or died during their work. Finally, in 1886, Henri Moissan isolated it.

Recherches sur l’isolement du fluor, Fig. 5.PNG
Recherches sur l’isolement du fluor, Fig. 5.PNG
He used a method called low-temperature electrolysis.

Fluorine is found in many places today. It is the 13th most common element in Earth's crust. Most of it comes from minerals like fluorite or fluorapatite. China and Mexico are major suppliers of these minerals. During World War II, the Manhattan Project used fluorine for uranium enrichment.

Uranium hexafluoride crystals sealed in an ampoule.jpg
Uranium hexafluoride crystals sealed in an ampoule.jpg
Today, companies sell over $15 billion of fluorochemicals every year. Some of these gases are greenhouse gases. One gas, SF6, has the highest global warming potential of any known substance.
SF6 current transformer TGFM-110 Russia.jpg
SF6 current transformer TGFM-110 Russia.jpg

You likely use fluorine every single day. Fluoride ions are added to toothpaste and water. These help to stop dental cavities in your teeth. It is also used to make Teflon for non-stick pans. Some medicines, like fluoxetine, contain fluorine bonds.

Prozac pills.jpg
Prozac pills.jpg
Even the way we make aluminium relies on fluorine compounds like cryolite. It is a small element with a huge impact on life.

443 words

Fluorine is a highly reactive chemical element with the symbol F and atomic number 9.

Fluorine molecule ball.svg
Fluorine molecule ball.svg
It is the lightest member of the halogen group. At standard conditions, it exists as a pale yellow diatomic gas. This means it is made of two atoms bonded together. Fluorine is famous for being extremely reactive. It will react with almost all other elements. The only exceptions are the light noble gases. Because of this intense reactivity, elemental fluorine is highly toxic. It is a powerful substance that plays many roles in modern industry and science.

The way fluorine behaves is driven by its unique atomic structure. A fluorine atom has nine electrons. Two electrons fill the inner shell, leaving seven in the outer shell. This outer shell requires only one more electron to become full. Because of this, fluorine has a very high electronegativity. This term describes how strongly an atom pulls on electrons. Fluorine has the highest electronegativity of any reactive element. It also has a high electron affinity, which is the tendency to capture an electron. This drive to complete its shell makes it react vigorously. While fluorine bonds easily with other atoms, the resulting carbon–fluorine bonds are often very stable.

Fluorine shows different physical states depending on the temperature. At room temperature, it is a pale yellow gas with a pungent, biting odor. If you cool it, it condenses into a bright yellow liquid at -188.1°C. It can also exist in two different solid forms: alpha-fluorine and beta-fluorine. Beta-fluorine is a transparent, soft solid with a disordered cubic structure. If you cool it even further, it undergoes a phase transition. It becomes alpha-fluorine, which is a hard, opaque solid with a monoclinic structure. This transition from beta to alpha is exothermic, meaning it releases heat, and can be quite violent.

Human history with fluorine began with the study of minerals. In 1529, Georgius Agricola described a mineral called fluorite. He used the Latin verb *fluorere*, meaning "to flow," to name it. This was because the mineral helped metal ores flow more easily during smelting. For centuries, people used fluorite to lower the melting points of metals. In 1810, the physicist André-Marie Ampère proposed the name "fluorine." However, isolating the pure element was incredibly difficult and dangerous. Many early researchers died or were injured while trying to separate it from its compounds. It was not until 1886 that Henri Moissan successfully isolated elemental fluorine.

Recherches sur l’isolement du fluor, Fig. 5.PNG
Recherches sur l’isolement du fluor, Fig. 5.PNG
He used a process called low-temperature electrolysis, which is still used today.

Fluorine is relatively rare in the universe. It ranks 24th in cosmic abundance, with a value of about 400 parts per billion. This low number is because fluorine is often bypassed during stellar nucleosynthesis. However, it is more common on Earth, where it ranks 13th in crustal abundance. Most fluorine on our planet is found in minerals like fluorite, fluorapatite, and cryolite.

Hall-Heroult cell schematic.svg
Hall-Heroult cell schematic.svg
China and Mexico are among the major global suppliers of these minerals. During World War II, the Manhattan Project began the industrial production of fluorine gas. This was necessary for the uranium enrichment process.

Today, the economic impact of fluorine is massive. Global sales of fluorochemicals exceed US$15 billion every year. Most commercial work uses fluorine compounds rather than the pure gas because refining the gas is expensive. About half of all mined fluorite is used in steelmaking. The rest is used to create hydrogen fluoride, which leads to various organic fluorides. Fluorine is also essential for making aluminium through the use of cryolite.

Uranium hexafluoride crystals sealed in an ampoule.jpg
Uranium hexafluoride crystals sealed in an ampoule.jpg
Some specialized gases, like sulfur hexafluoride (SF6), are used in electrical equipment.
SF6 current transformer TGFM-110 Russia.jpg
SF6 current transformer TGFM-110 Russia.jpg

You encounter fluorine in many unexpected places. In medicine, drugs like atorvastatin and fluoxetine contain carbon–fluorine bonds.

Prozac pills.jpg
Prozac pills.jpg
In your home, Teflon is a common organofluorine compound used for non-stick surfaces. Fluoride ions are also added to toothpaste and drinking water to prevent dental cavities.
US Navy 090526-F-1333S-023 A service member embarked aboard the Military Sealift Command hospital ship USNS Comfort (T-AH 20) gives a Fluoride treatment to a patient during a Continuing Promise 2009 medical civil service projec.jpg
US Navy 090526-F-1333S-023 A service member embarked aboard the Military Sealift Command hospital ship USNS Comfort (T-AH 20) gives a Fluoride treatment to a patient during a Continuing Promise 2009 medical civil service projec.jpg
However, there are environmental concerns to consider. Many fluorocarbon gases are potent greenhouse gases. SF6, for example, has a global warming potential up to 23,500 times higher than carbon dioxide. Because the carbon–fluorine bond is so strong, these compounds can persist in the environment for a long time.

750 words
🖼️ Images & Media (24)
File:Fluorine molecule ball.svg
Fluorine molecule ball.svg
File:Beta fluorine unit cell.svg
Beta fluorine unit cell.svg
File:Beta-fluorine crystal structure.gif
Beta-fluorine crystal structure.gif
File:Book9-25.gif
Book9-25.gif
File:Recherches sur l’isolement du fluor, Fig. 5.PNG
Recherches sur l’isolement du fluor, Fig. 5.PNG
File:Uranium hexafluoride crystals sealed in an ampoule.jpg
Uranium hexafluoride crystals sealed in...
File:Sodium-fluoride-unit-cell-3D.png
Sodium-fluoride-unit-cell-3D.png
File:Bismuth-pentafluoride-chain-from-xtal-1971-3D-balls.png
Bismuth-pentafluoride-chain-from-xtal-1971...
File:Rhenium-heptafluoride-3D-balls.png
Rhenium-heptafluoride-3D-balls.png
File:Boiling-points Chalcogen-Halogen.svg
Boiling-points Chalcogen-Halogen.svg
File:Chlorine-trifluoride-3D-balls.png
Chlorine-trifluoride-3D-balls.png
File:Xenon tetrafluoride crop.gif
Xenon tetrafluoride crop.gif

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